Kinetic Resolution of Enantiomers in Enantiomerically Enriched 2-Alkanol by Pseudomonas cepacia Lipase Catalyzed Transesterification with Vinyl Acetate in Organic Solvent.
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چکیده
منابع مشابه
Pseudomonas cepacia lipase--mediated transesterification reactions of hydrocinnamates.
Use of lipase from Pseudomonas cepacia in transesterifcation reactions of ethyl hydrocinnamate with different alcohols has been examined. Among the alcohols tested, viz., n-butanol, iso-amyl alcohol, benzyl alcohol, n-octanol and 1-phenylethanol, only n-butanol yielded the transesterified product. Among the solvents tested, viz., n-heptane, n-hexane, cyclohexane, toluene, diisopropylether and n...
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Racemic 1-(β-hydroxypropyl)azoles were prepared by solvent-free direct regioselective ring opening of 1,2-propylene oxide with imidazole or 1,2,4-triazole. Lipase-catalyzed transesterification of alcohols with vinyl acetate resulted in kinetic enantiomers resolution. Separated (S)-enantiomers of (+)-1-(1H-imidazol-1-yl)propan-2-ol and (+)-1-(1H-1,2,4-triazol-1-yl)propan-2-ol were quaternized wi...
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Porcine pancreatic lipase (PPL), a comparatively inexpensive enzyme, was used in the optical resolution of (R, S)ibuprofen in methanol through enantioselective esterification. The different reaction parameters during the esterification of (R, S)-ibuprofen using PPL was studied with respect to temperature, time, enzyme concentration, substrate concentration and water content. The percentage conv...
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متن کاملPorcine pancreas lipase catalyzed synthesis of lauryl laurate in organic solvent media: A kinetic study
The esterification of lauric acid with lauryl alcohol was studied using lipase from Porcine pancreas, with particular emphasis on the effect of the pertinent variables and kinetic aspects of the reaction. The reaction was studied in eight different solvents having hydrophobicity (the logarithm of octanol-water partition coefficient, log P) values ranging from 0.6 to 3.5 with constant water cont...
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ژورنال
عنوان ژورنال: Journal of Oleo Science
سال: 2003
ISSN: 1345-8957,1347-3352
DOI: 10.5650/jos.52.99